1757-1763 Ivan I. Shuvalov
1763-1794 Ivan I. Betskyi
1794-1797 Alexei I. Musin-Pushkin
1797-1800 Marie Gabriel Florent Auguste de Choiseul-Gouffier
1800-1811 Alexander S. Stroganov
1817-1843 Alexei N. Olenin
1843-1852 Maximilian Leichtenberg
1852-1876 Great Duchess Maria Nikolaevna
1876-1909 Grand Duke Vladimir Alexandrovich
1909-1917 Grand Duchess Maria Pavlovna
1934-1939 Issak I. Brodski
1947-1957 Alexander M. Gerasimov
1958-1962 Boris V. Ioganson
1962-1968 Vladimir A. Serov
1968-1983 Nickolai V. Tomski
1983-1991 Boris S. Ugarov
1992-1997 Nicholai A. Ponomarev
1997 – present Zurab K. Tsereteli
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